Thanks cjmnews,No. iTunes only recognizes iPod, iPhones and iPads.
You can however, use iTunes to hold your music, and put it onto an MP3 player by opening a Windows Explorer window in the MP3 player, then selecting the tracks you want from iTunes, drag them from iTunes and drop them onto Windows Explorer. That will copy the files from iTunes to the MP3 player.
There are some limitations though. No smart playlists will work, no iTunes playlists will work, the MP3 player has to support AAC to play unencrypted m4a files. No encrypted m4a, m4p or m4b files will be able to play. Remembering your position in a file will not work.